Carboxylic groups created on a surface after uv ozone activation can be used to bind molecules via amide bond. Stability of uvozonetreated thermoplastics under different storage. Recently, i kept two pdms devices inside for treatment, one got treated with contact angle reduced to 30 degrees but other one just reduced to 58 degrees from 104 degrees after 2 hrs of treatment. Uvo treatment is a photosensitized oxidation process in which the molecules of the treated material are excited andor dissociated by the absorp. Pdms films without any treatment, but that change was 400% for films. Wettability control and patterning of pdms using uvozone. I am trying to get a pdms pdms bonding with oxygen plasma treatment. Ultravioletozone uvo treatment the ultravioletozone uvo treatment of the pdms surface was carried out in a commercial uvo chamber jelight company, inc. In this study application of uv ozone treatment to fabrication of microfluidic devices has been presented.
The influence of plasma treatment on the elasticity of the in situ. A novascan psd series digital uv ozone system was used to irradiate samples at a uv bulbtosample height of 5 mm. Nonplasma bonding of pdms for inexpensive fabrication of microfluidic devices joseph harris 1, hyuna lee 1, behrad vahidi 1, cristina tu 2, david cribbs 3, carl cotman 3, noo li jeon 1. We show that a uvozone precleaning of the pdms surface. Uvozone surface treatment increases hydrophilicity and. Timedependent uv ozone treatment increases hydrophilicity of the su8 film without affecting the surface roughness. The use of uvozone surface treatments for achieving low temperature bonds between pmma and coc. Effect of uvozone treatment on polydimethylsiloxane. Additionally, the use of a photomask makes it convenient to pattern the wettability in the porous media. Nonplasma bonding of pdms for inexpensive fabrication of. I want to modify the surface of pdms into hydrophilic for which i am thinking of doing uvozone treatment. Does this treatment cause any crack formation on pdms. Gas permeation measurements on the uvozone exposure pdms membranes documented interesting gas separation properties. In this method, uvozone treatment is utilized to oxidize and hydrophilize the surface of pdms.
Immobilized molecules are accessible for further reactions or subsequent interactions with macromolecules. Surface modification of sylgard184 polydimethyl siloxane. To maintain a stable surface wettability, the oxidized surfaces are immersed in water. Even though 254nm uv light dissociates ozone and forms singlet atomic oxygen, the reactive species has short lifetime around 10 ms. Therefore, the density of singlet atomic oxygen is a bottleneck in uvozone cleaning process. Pdms can be converted into a silicalike material by uv ozone treatment enabling much deeper oxidation of pdms without crack failures compared to oxygen plasma treatment. Wettability control and patterning of pdms using uvozone and. Ultraviolet uv ozone treatment uvozone treatment is also known as uvozone activating, which is a surface activating process of sample or substrate used in material and device fabrication. The ultraviolet ozone uvo treatment of the pdms sur. Pdms surfaces were cleaned by sonicating in ethanol for 10 min then ozone treated 3 days after curing. Stage temperature is also one of the important factors in uvozone treatment. In this process, photochemical reaction happens on the surfaces and substrates of the materials. Uvozone uvo treatment is a simple and effective method for making plastic.
Selective ozone treatment of pdms printing stamps for. Effect of ultravioletozone treatment on the surface and bulk properties of. Effect of ultravioletozone treatment on the surface and bulk. For instance, uvozone methods currently require two spectral lines, the first to.
1166 549 1511 166 524 163 1128 509 1537 1526 1516 1486 1234 1389 1116 697 1484 1606 1618 1574 281 603 1309 810 957 1186 432 315 334 381 602 685 553 960 1604 788 328 166 1185 249 909 491 1001 1279 936 359 222 619